EPEL & Remi Repository
yum localin­stall –nogpgcheck http://download.fedoraproject.org/pub/epel/6/i386/epel-release‑6–8.noarch.rpm
yum localin­stall –nogpgcheck http://rpms.famillecollet.com/enterprise/remi-release‑6.rpm

RPM­Fu­sion Repository
yum localin­stall –nogpgcheck http://download1.rpmfusion.org/free/el/updates/6/i386/rpmfusion-free-release‑6–1.noarch.rpm
yum localin­stall –nogpgcheck http://download1.rpmfusion.org/nonfree/el/updates/6/i386/rpmfusion-nonfree-release‑6–1.noarch.rpm

Check the Avail­abil­i­ty of VLC
yum –enablerepo=remi-test info vlc

Install VLC
yum –enablerepo=remi-test install vlc

UPDATE :
yum –enablerepo=remi-test update vlc

SORUCE : http://www.tecmint.com
!! VLC is not sup­posed to be run as root use !!